Energy and Structure

Description
The themes of energy and structure are used to examine aspects of applied physical chemistry with a focus on the relationship between macroscopic properties and molecular-scale structure. Electrode dynamics, including the metal-solution interface and structure of the double layer, is examined, along with rates and mechanisms of charge transfer reactions, electrochemical techniques and corrosion. Key surface chemistry concepts are introduced, including the role of surface energy and adsorption of molecules at phase boundaries or interfaces. Surfactant self-assembly into soft materials including micelles, liquid crystals and microemulsions is examined, and the relationship between these structures and those formed by room temperature ionic liquids is explained.

Learning outcomes
On successful completion of the course students will be able to:

1. Developed expertise relevant to the professional practice of chemistry;

2. A greater understanding of the range of physical processes operating in chemistry;

3. Developed a deeper understanding of the methods and theories of applied physical chemistry;

4. An understanding of the role of the physical chemist in the interpretation of physical and chemical phenomena;

5. An understanding of the concepts of electrode dynamics, surface chemistry, and soft matter;

6. Laboratory experience with some methods employed in applied physical chemistry;

7. Expanded skills in the scientific method of planning, developing, conducting, reviewing and reporting experiments;

8. An extended understanding of the professional and safety responsibilities residing in working with hazardous substances.

Content
The course involves study of:

ELECTRODE DYNAMICS:

• the electrically charged interface
• charge transfer at the interface
• multi-step charge transfer processes
• mass transport control
• experimental techniques
• corrosion

SURFACE CHEMISTRY:

• surface energy
• adsorption
• the solid-gas interface
• the solid-liquid interface
• the liquid-gas interface

SOFT MATTER:

• surfactants, micelles and adsorption
• liquid crystals
• emulsions and microemulsions
• room temperature ionic liquids

Contact hours
Laboratory
Face to Face On Campus 3 hour(s) per Week for 12 Weeks

Lecture
Face to Face On Campus 2 hour(s) per Week for 12 Weeks

Tutorial
Face to Face On Campus 1 hour(s) per Week for 12 Weeks